Technical Ceramics

Zirconia (ZrO2)

Yttria Stabilised Zirconia

Morgan Technical Ceramics offers injection mouldable yttria stabilised zirconia ceramic for the medical industry. Within medical applications, zirconia ceramic offers a highly wear resistant and more biocompatible solution vs titanium which can cause an allergic reactions within certain patients.

Additionally, with the onset of smart monitoring, implant cases made of Zirconia do not suffer from magnetic and electrical interference the same way metallic cases do in certain environments. This allows patients to safely and reliably measure & monitor bodily functions through wireless means. Grades compliant to ISO 13356 implant standard are available within our portfolio.

Material Properties

General

Colour

White

Density

g/cm3

>6.0

Porosity (apparent)

% nominal

0 (fully dense)

Rockwell hardness (R45N)

%

87

Fracture toughness

MPa.m1/2

10

Flexural strength (4-point)

MPa @20°C

>800

Grain size

μm

0.2

Young's modulus E

GPa @20°C

220

Thermal

Thermal conductivity

W/mK @20°C

2.9

Thermal expansion coefficient

106 @20-1000°C

9.0

Thermal shock resistance (R1)

∆T/°C

400

Thermal shock resistance (R2)

W/m

891

Specific heat

J/kg.K

610

Electric

Permittivity

10 GHz @20°C

33

Volume resistivity

ohm.cm @100°C

>1010

Nilcra® Zirconia

Nilcra® Zirconia is a range of 'transformation toughened' ceramics that are inert to most chemicals, have exceptional strength, have high toughness and reliability which together result in outstanding resistance to wear and corrosion.

Nilcra® Zirconia’s are frequently used to replace conventional metal alloys, hardened steels and tungsten carbides that suffer from wear and corrosion.

Nilcra® Zirconia’s are used in a wide variety of industries experiencing high maintenance costs, high downtime costs and poor product quality from lack of process control.

Industries as diverse as oil and gas, mining, food and battery production have enjoyed the benefits of long life, high production rates and low maintenance.

Our grades of Nilcra® Zirconia include:

Magnesia - Partially Stabilised Zirconia (Mg-PSZ) – Highest toughness grades:

These are the most reliable grades of ceramic in the world (Weibull modulus of >30) thereby providing peace of mind that Mg-PSZ components will perform the same every time and allowing engineers to utilise with confidence a much higher percentage of the published material strength compared to that of brittle ceramics.

  • Nilcra® Zirconia MS – 'Maximum Strength' grade ideal for wear and corrosion solutions and used extensively in materials handling industries.
  • Nilcra® Zirconia TS – 'Thermal Shock' grade provides high resistance to thermal shock and is used in non-ferrous metal extrusion applications.

Yttria - Tetragonal Zirconia Polycrystal (Y-TZP) - Highest strength and hardness grades with a finer grain structure:

Learn about our Zirconia solutions:

 

 

Physical properties

Nilcra® Zirconia MS

Nilcra® Zirconia TS

Nilcra® Zirconia 3Y-TZP

Nilcra® Zirconia HIP’ed 3Y-TZP

Colour

White

White

White

Grey

Density

g/cm3

5.74

5.74

6.07

6.08

@20°C

Flexural strength

MPa

820

650
360

1000

1400

@20°C
@820°C

Compressive strength

MPa

1990

1800
1750

2300

2300

@20°C
@800°C

Tensile strength

MPa

430

390

@20°C

Weibull modulus

>30

>30

@20°C

Modulus of elasticity

GPa

205

205

205

205

@20°C

Poisson's ratio

0.31

0.31

0.3

0.3

@20°C

Hardness

HV0.3 kg/mm2

1120

1020

1300

1350

@20°C

Hardness Rockwell

45N

82

@20°C

Fracture Toughness

MPa√m 

12

15

10

10

@20°C

Average grain size

μm

40

45

0.4

0.4

Maximum use temperature

°C

800

800

800

Thermal shock resistance

∆T °C

375

500

200

Electrical resistivity

Ohm.com

>1011
3.3x104
5000
100

>1011
1.9x105
2.7x104
8000

>1011

>1011

@20°C
@500°C
@600°C
@900°C

Thermal conductivity

W/m.K

3.08
2.44
2.26

3.05
2.47
2.32

3.0

3.0

@20°C
@400°C
@800°C

Thermal expansion coefficient

x10-6 mm/mm/°C

10.2
10.2

9.9
9.7

9.0

9.0

25-400°C
25-800°C

Specific heat capacity 

J/g.K

0.47

0.47

0.5

0.5

@20°C